Title
Enhanced growth rate of atmospheric particles from sulfuric acid
Author
Mario Simon
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt
Author
Ananth Ranjithkumar
School of Earth and Environment, University of Leeds
... show all
Abstract
In the present-day atmosphere, sulfuric acid is the most important vapour for aerosol particle formation and initial growth. However, the growth rates of nanoparticles (<10 nm) from sulfuric acid remain poorly measured. Therefore, the effect of stabilizing bases, the contribution of ions and the impact of attractive forces on molecular collisions are under debate. Here, we present precise growth rate measurements of uncharged sulfuric acid particles from 1.8 to 10 nm, performed under atmospheric conditions in the CERN (European Organization for Nuclear Research) CLOUD chamber. Our results show that the evaporation of sulfuric acid particles above 2 nm is negligible, and growth proceeds kinetically even at low ammonia concentrations. The experimental growth rates exceed the hard-sphere kinetic limit for the condensation of sulfuric acid. We demonstrate that this results from van der Waals forces between the vapour molecules and particles and disentangle it from charge–dipole interactions. The magnitude of the enhancement depends on the assumed particle hydration and collision kinetics but is increasingly important at smaller sizes, resulting in a steep rise in the observed growth rates with decreasing size. Including the experimental results in a global model, we find that the enhanced growth rate of sulfuric acid particles increases the predicted particle number concentrations in the upper free troposphere by more than 50 %.
Keywords
Atmospheric Science
Object type
Language
English [eng]
Persistent identifier
https://phaidra.univie.ac.at/o:1178768
Appeared in
Title
Atmospheric Chemistry and Physics
Volume
20
Issue
12
ISSN
1680-7324
Issued
2020
From page
7359
To page
7372
Publisher
Copernicus GmbH
Date issued
2020
Access rights
Rights statement
© Author(s) 2020

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