Title
Survival of newly formed particles in haze conditions
Author
Ruby Marten
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute
Author
Mao Xiao
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute
Author
Birte Rörup
Institute for Atmospheric and Earth System Research (INAR)/Physics, Faculty of Science, University of Helsinki
... show all
Abstract
Intense new particle formation events are regularly observed under highly polluted conditions, despite the high loss rates of nucleated clusters. Higher than expected cluster survival probability implies either ineffective scavenging by pre-existing particles or missing growth mechanisms. Here we present experiments performed in the CLOUD chamber at CERN showing particle formation from a mixture of anthropogenic vapours, under condensation sinks typical of haze conditions, up to 0.1 s−1. We find that new particle formation rates substantially decrease at higher concentrations of pre-existing particles, demonstrating experimentally for the first time that molecular clusters are efficiently scavenged by larger sized particles. Additionally, we demonstrate that in the presence of supersaturated gas-phase nitric acid (HNO3) and ammonia (NH3), freshly nucleated particles can grow extremely rapidly, maintaining a high particle number concentration, even in the presence of a high condensation sink. Such high growth rates may explain the high survival probability of freshly formed particles under haze conditions. We identify under what typical urban conditions HNO3 and NH3 can be expected to contribute to particle survival during haze.
Keywords
PollutionEnvironmental ChemistryChemistry (miscellaneous)Analytical Chemistry
Object type
Language
English [eng]
Persistent identifier
https://phaidra.univie.ac.at/o:1679384
Appeared in
Title
Environmental Science: Atmospheres
Volume
2
Issue
3
ISSN
2634-3606
Issued
2022
From page
491
To page
499
Publisher
Royal Society of Chemistry (RSC)
Date issued
2022
Access rights
Rights statement
© 2022 The Author(s)
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