Title
Adsorption characteristics of Janus tadpole polymers
Abstract
The shape of Janus particles is directly connected to their adsorption behavior. Janus tadpole polymers offer a unique topological architecture that includes competition between entropic, enthalpic, and topological terms in the adsorption free energy; accordingly, non-trivial adsorption behavior patterns are expected. We study the surface adsorption of Janus tadpole polymers by means of Monte Carlo simulations, finding that, depending on which part of the tadpole polymers is preferentially adsorbing on the surface, very different types of behavior for both the adsorbed polymeric phase and of the brush arise. The adsorbed phase and the brush mutually influence each other, leading to a variety of phenomena such as nematic ordering of the adsorbed stiff tadpole tails and intriguing changes in the territoriality of adsorbed ring polymers on the surface. We analyze in detail our findings, revealing the mechanisms behind the organization and ordering, and opening up new possibilities to tune and control the structure of such systems.
Keywords
Gyration radiusLiquid crystal phasesFlexural rigidityMonte Carlo methodsJanus particlesAdsorptionPolymers
Object type
Language
English [eng]
Persistent identifier
https://phaidra.univie.ac.at/o:2086422
Appeared in
Title
The Journal of Chemical Physics
Volume
160
Issue
22
ISSN
0021-9606
Issued
2024
Publisher
AIP Publishing
Date issued
2024
Access rights
Rights statement
© 2024 Author(s)

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