Titel
Total Synthesis, Stereochemical Assignment, and Divergent Enantioselective Enzymatic Recognition of Larreatricin
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Abstract
A concise and efficient total synthesis of the lignan natural product larreatricin as well as an unambiguous assignment of configuration of its enantiomers are reported, resolving a long‐held controversy. Enzyme kinetic studies revealed that different polyphenol oxidases show high and remarkably divergent enantioselective recognition of this secondary metabolite.
Stichwort
enantiospecifickineticslarreatricinpolyphenol oxidasetotal synthesis
Objekt-Typ
Sprache
Englisch [eng]
Persistent identifier
https://phaidra.univie.ac.at/o:996641
Erschienen in
Titel
Chemistry - A European Journal
Band
24
Ausgabe
59
Seitenanfang
15756
Seitenende
15760
Verlag
Wiley
Erscheinungsdatum
2018
Zugänglichkeit
Rechteangabe
© 2017 The Authors

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