Title
The ternary phase Li8SbxSn3-x with 0.3 ≤ x ≤ 1.0
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Abstract
In the frame of the studies on the phase relations in the ternary system Li–Sb–Sn at 300 °C the new ternary phase Li8SbxSn3-x (0.3 ≤ x ≤ 1.0) was synthesized and characterized predominantly by single crystal and powder X-ray diffraction. The title compound crystallizes trigonally in the space group R ¯3m (no. 166), the lattice parameters are a = 4.6962(11) Å and c = 31.536(6) Å. The crystal structure of Li8SbxSn3-x is described in the present paper. In addition, the stereochemical and topological relations to the phases with similar composition, namely Li13Sn5, Li5Sn2 as well as cubic Li3Sb, besides native Li are discussed.
Keywords
crystal structurehexacapped cubeLi–Sb–SnLi8SbxSn3-xX-ray diffraction
Object type
Language
English [eng]
Persistent identifier
https://phaidra.univie.ac.at/o:1214185
Appeared in
Title
Zeitschrift für Kristallographie - Crystalline Materials
Volume
235
Issue
6-7
ISSN
2196-7105
Issued
2020
From page
183
To page
192
Publisher
Walter de Gruyter GmbH
Date issued
2020
Access rights
Rights statement
© 2020 Patric Berger et al

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