Titel
The ternary phase Li8SbxSn3-x with 0.3 ≤ x ≤ 1.0
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Abstract
In the frame of the studies on the phase relations in the ternary system Li–Sb–Sn at 300 °C the new ternary phase Li8SbxSn3-x (0.3 ≤ x ≤ 1.0) was synthesized and characterized predominantly by single crystal and powder X-ray diffraction. The title compound crystallizes trigonally in the space group R ¯3m (no. 166), the lattice parameters are a = 4.6962(11) Å and c = 31.536(6) Å. The crystal structure of Li8SbxSn3-x is described in the present paper. In addition, the stereochemical and topological relations to the phases with similar composition, namely Li13Sn5, Li5Sn2 as well as cubic Li3Sb, besides native Li are discussed.
Stichwort
crystal structurehexacapped cubeLi–Sb–SnLi8SbxSn3-xX-ray diffraction
Objekt-Typ
Sprache
Englisch [eng]
Persistent identifier
https://phaidra.univie.ac.at/o:1214185
Erschienen in
Titel
Zeitschrift für Kristallographie - Crystalline Materials
Band
235
Ausgabe
6-7
ISSN
2196-7105
Erscheinungsdatum
2020
Seitenanfang
183
Seitenende
192
Verlag
Walter de Gruyter GmbH
Erscheinungsdatum
2020
Zugänglichkeit
Rechteangabe
© 2020 Patric Berger et al

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