Retraction Note: Precise determination of graphene functionalization by in situ Raman spectroscopy

Philipp Vecera; Julio C. Chacón-Torres; Thomas Pichler; Stephanie Reich; Himadri R. Soni; Andreas Görling; Konstantin Edelthalhammer; Herwig Peterlik; Frank Hauke; Andreas Hirsch

doi:10.1038/s41467-022-34281-x

Titel

Retraction Note: Precise determination of graphene functionalization by in situ Raman spectroscopy

Autor*in

Philipp Vecera

Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander University of Erlangen-Nuremberg

Julio C. Chacón-Torres

Institut für Experimental Physik, Freie Universität Berlin

Thomas Pichler

Fakultät für Physik, Universität Wien

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Abstract

Retraction to: Nature Communications doi.org/10.1038/ncomms15192, published online 08 May 2017 The authors have retracted this article because of data processing errors that impacted data presentation and interpretation of the Raman spectra plotted in Fig. 1c, Fig. 2b, and Fig. S2, which invalidate the conclusions of the article. The authors state that the data processing was performed with a routine implemented in the OriginPro® software. The evolution of the Raman spectra upon exposure to an electrophilic trapping reagent (H20 vapour, H2, O2) was displayed as cumulative plots, whereby individual spectra are added up consecutively and displayed in a ‘waterfall’ presentation. Upon re-examination of the data, the authors found that the Cz mode, characteristic of graphitic intercalation, vanishes with the continuous exposure of the electrophilic trapping reagent, whereas in the original Fig. 1c, Fig. S2 it is widely retained, and in some series it becomes more intense. The apparent persistence of the Cz mode is a direct consequence of the erroneous data processing. Any conclusions on the structure of the intercalated graphite during gas exposure that were drawn from the analysis of the Cz mode are invalid. Especially, pathway i) in Fig.2a of the paper is not supported by the measured data. Furthermore, the authors found that the spectra displayed in Fig. 1d, Fig. 2b (grey line) and Fig. 4b are identical, although they are described as different data sets, invalidating the analysis of the D bands. All authors agree to this retraction.

Stichwort

General Physics and AstronomyGeneral Biochemistry, Genetics and Molecular BiologyGeneral ChemistryMultidisciplinary

Objekt-Typ

journal article

Sprache

Englisch [eng]

Persistent identifier

phaidra.univie.ac.at/o:1681656

DOI

10.1038/s41467-022-34281-x

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