Titel
Crystal structure of the tetragonal polymorph of bis(1-ethyl-3-methylimidazolium) tetrabromidocadmate
Autor*in
Ljiljana Karanović
Universität Belgrad
Abstract
Both unique Cd atoms in the tetra­gonal polymorph of bis­(1-ethyl-3-methyl­imidazolium) tetra­bromido­cadmate, (C6H11N2)2[CdBr4], occupy special positions (site symmetry -4). The crystal structure consists of isolated tetra­hedral [CdBr4]2- anions which are surrounded by 1-ethyl-3-methyl­imidazolium cations. The methyl and ethyl side chains of the cations show positional disorder in a 0.590 (11):0.410 (11) ratio. In the crystal, (C6H11N2)+ cations display three weak C-H...Br hydrogen-bond inter­actions through the imidazolium ring H atoms with the Br- ligands of the surrounding complex anions. The alkyl groups of the side chains are not involved in hydrogen bonding.
Objekt-Typ
Sprache
Englisch [eng]
Persistent identifier
https://phaidra.univie.ac.at/o:474339
Erschienen in
Titel
Acta Crystallographica Section E, Crystallographic Communications
Band
72
Ausgabe
7
Seitenanfang
1013
Seitenende
1016
Verlag
International Union of Crystallography (IUCr)
Erscheinungsdatum
2016
Zugänglichkeit

Herunterladen

Universität Wien | Universitätsring 1 | 1010 Wien | T +43-1-4277-0